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SOP for Labeling and Signage of Hazardous Materials

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SOP for Labeling and Signage of Hazardous Materials

Standard Operating Procedure for Labeling and Signage of Hazardous Materials

1) Purpose

The purpose of this SOP is to ensure that all hazardous materials within the facility are appropriately labeled and signposted. Proper labeling and signage help identify hazards, prevent mishandling, and comply with safety regulations.

2) Scope

This SOP applies to all hazardous materials received, stored, used, and transported within the facility. It includes requirements for primary and secondary container labeling as well as area signage for hazardous zones.

3) Responsibilities

  • Operators: Ensure proper labeling of all containers used during operations.
  • Quality Assurance (QA): Verify that all hazardous materials are labeled and signposted appropriately.
  • Safety Officers: Oversee compliance with labeling standards and signage requirements.
  • Inventory Managers: Maintain updated records of labeled materials and their corresponding SDS.

4) Procedure

4.1 Labeling of Hazardous Materials

Proper labeling is essential to ensure hazardous materials are identified correctly during handling, storage, and transport. Follow the steps below:

  1. Primary Container Labeling:
    1. Verify that each primary container provided by the supplier includes:
      • Material name and trade name
      • Hazard classification (e.g., flammable, toxic, corrosive)
      • Signal words: “Danger” or “Warning”
      • GHS (Globally Harmonized System) pictograms
      • Supplier name and contact information
      • Precautionary and hazard statements
    2. If any label is illegible, damaged, or missing:
      • Isolate the container in a designated area.
      • Notify the supervisor and relabel the container using approved labeling guidelines.
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  3. Secondary Container Labeling:
    1. When transferring hazardous materials to secondary containers, label the new container immediately.
    2. The label must include the following details:
      • Material name
      • Hazard classification
      • GHS pictogram(s)
      • Signal word (e.g., “Warning” or “Danger”)
      • Date of transfer
      • Initials of the person handling the transfer
    3. Do not use generic or incomplete labels (e.g., “Chemical X”).
  4. Temporary Labels:
    1. For short-term use (less than 24 hours), temporary labels must include at least:
      • Material name
      • Hazard classification
    2. All temporary labels must be removed or replaced with permanent labels when work is complete.
  5. Inspection and Maintenance of Labels:
    1. Inspect all containers weekly to ensure labels are legible and intact.
    2. Replace labels immediately if they are faded, damaged, or missing.
See also  SOP for Filing and Archiving Safety Data Sheets (SDS)

4.2 Signage for Hazardous Areas

Signage must be displayed in all areas where hazardous materials are stored, used, or transported. Follow these guidelines for proper signage:

  1. Placement of Signs:
    1. Place clear and visible signs at the entrances to hazardous material storage areas, laboratories, and other high-risk zones.
    2. Position signage at eye level and avoid obstructions.
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  3. Types of Signs:
    1. Use appropriate GHS pictograms for hazard classifications, such as:
      • Flame (flammables)
      • Skull and crossbones (toxic materials)
      • Corrosion (corrosive substances)
      • Exclamation mark (irritants, sensitizers)
    2. Warning or caution signs must include:
      • “DANGER” for severe hazards
      • “CAUTION” for moderate hazards
      • “NOTICE” for informational purposes
  4. Color Coding:
    • Red: Flammable materials
    • Yellow: Reactive and explosive materials
    • Blue: Health hazards
    • Green: Safety equipment and first aid
  5. Inspection and Maintenance of Signs:
    1. Conduct weekly checks to ensure all hazard signs are visible, intact, and accurate.
    2. Replace faded, damaged, or outdated signage immediately.
See also  SOP for Managing Waste During Emergency Shutdowns

4.3 Training and Monitoring

  1. Employee Training:
    1. Train all employees on the importance of labeling and signage for hazardous materials.
    2. Include the following in training programs:
      • How to interpret GHS pictograms
      • Proper labeling of primary and secondary containers
      • Signage placement and meaning
      • Reporting damaged or missing labels/signs
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  3. Monitoring Compliance:
    1. QA and safety officers must conduct monthly audits of labels and signage.
    2. Document and address any non-compliance during inspections.

5) Abbreviations, if any

  • GHS: Globally Harmonized System
  • PPE: Personal Protective Equipment
  • SDS: Safety Data Sheet
  • QA: Quality Assurance

6) Documents, if any

  • Hazardous Material Labeling Inspection Log
  • Signage Inspection Checklist
  • Safety Data Sheets (SDS)
See also  SOP for Containing and Managing Explosions in Hazardous Areas

7) Reference, if any

  • OSHA Hazard Communication Standard (29 CFR 1910.1200)
  • Globally Harmonized System (GHS) of Classification and Labeling
  • ISO 3864-2: Safety Signs and Symbols

8) SOP Version

Version: 1.0

Annexure

Template 1: Hazardous Material Labeling Inspection Log

 
Date Material Name Container Type Label Condition Inspected By
DD/MM/YYYY Chemical Name Primary/Secondary Good/Damaged/Missing Inspector Name

Template 2: Signage Inspection Checklist

 
Date Location Sign Type Condition Inspected By
DD/MM/YYYY Hazardous Storage Area Flammable/Corrosive/Toxic Good/Damaged/Missing Inspector Name
Environment, Health and Safety Tags:Emergency response for hazardous materials incidents, Hazardous materials classification, Hazardous materials compliance audits, Hazardous materials decontamination procedures, Hazardous materials disposal methods, Hazardous materials emergency planning, Hazardous materials emergency response guidebook, Hazardous materials exposure limits, Hazardous materials handling, Hazardous materials handling equipment, Hazardous materials incident command system, Hazardous materials incident reporting, Hazardous materials inventory management, Hazardous materials labeling requirements, Hazardous materials monitoring equipment, Hazardous materials packaging requirements, Hazardous materials placarding requirements, Hazardous materials regulatory agencies, Hazardous materials response team training, Hazardous materials risk assessment, Hazardous materials security plans, Hazardous materials shipping papers, Hazardous materials spill response, Hazardous materials storage guidelines, Hazardous materials training requirements, Hazardous materials transportation regulations, Hazardous materials transportation safety, Personal protective equipment for hazardous materials, Regulatory compliance in hazardous materials management, Safety procedures for hazardous materials

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Standard Operating Procedures V 1.0

  • Aerosols
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NEW! Revised SOPs – V 2.0

  • Aerosols V 2.0
  • Analytical Method Development V 2.0
  • API Manufacturing V 2.0
  • BA-BE Studies V 2.0
  • Biosimilars V 2.0
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