SOP Guide for Pharma

API Manufacturing: SOP for Segregation and Disposal of Hazardous Waste – V 2.0

API Manufacturing: SOP for Segregation and Disposal of Hazardous Waste – V 2.0

Standard Operating Procedure for Segregation and Disposal of Hazardous Waste in API Manufacturing

Department API Manufacturing
SOP No. SOP/API/203/2025
Supersedes SOP/API/203/2022
Page No. Page 1 of 14
Issue Date 14/04/2025
Effective Date 16/04/2025
Review Date 14/04/2026

1. Purpose

To define the procedures for the identification, segregation, labeling, temporary storage, transportation, and disposal of hazardous waste generated in API manufacturing operations in accordance with GMP, CPCB, and environmental safety guidelines.

2. Scope

This SOP applies to all departments within the API manufacturing facility involved in the handling of hazardous waste, including solvents, contaminated materials,

expired chemicals, and rejected intermediates. It includes both production and warehouse areas.

3. Responsibilities

  • Production & Warehouse Personnel: Identify and segregate hazardous waste at source.
  • EHS Department: Manage waste labeling, documentation, temporary storage, and disposal.
  • QA Department: Ensure compliance with SOP and maintain oversight of waste handling records.
  • Approved Vendors: Transport and dispose hazardous waste as per legal requirements.

4. Accountability

The Head of EHS is accountable for ensuring hazardous waste disposal complies with statutory regulations, and that internal handling meets GMP and site safety standards.

5. Procedure

5.1 Identification of Hazardous Waste

  1. Types of hazardous waste generated:
    • Spent solvents and solvent mixtures
    • Contaminated PPE or spill absorbents
    • Expired or off-spec chemicals
    • Rejected batches or intermediates
    • Used lab reagents and glassware
  2. Material Safety Data Sheets (SDS) must be consulted to confirm hazard classification.

5.2 Segregation Guidelines

  1. Segregate waste at point of generation using:
    • Red containers – Flammable/Organic solvent waste
    • Yellow containers – Reactive or corrosive chemicals
    • Black bags – Contaminated solid waste (e.g., gloves, wipes)
  2. Ensure incompatible substances are not mixed (e.g., acids with bases).
  3. Place spill-proof labels on all containers (see Annexure-1).

5.3 Labeling and Documentation

  1. Each hazardous waste container must have:
    • Waste description
    • Date of generation
    • Hazard classification
    • Department and responsible person
  2. Use the Hazardous Waste Tag format provided in Annexure-1.
  3. Record entries in the Hazardous Waste Register (Annexure-2).

5.4 Temporary Storage

  1. Transfer containers to the Hazardous Waste Storage Room once 75% full or within 7 days.
  2. Storage area must:
    • Be well-ventilated
    • Have spill containment pallets
    • Be secured and access-controlled
  3. Post appropriate hazard signage (see Annexure-3).

5.5 Disposal Process

  1. Disposal is permitted only via authorized and licensed vendors (listed in Annexure-4).
  2. Vendor shall:
    • Provide manifest form as per Hazardous Waste Management Rules
    • Transport waste in DG-compliant containers
  3. Maintain copies of disposal records and manifest in the Hazardous Waste Disposal File.

5.6 Handling Precautions

  1. Personnel handling waste must wear:
    • Nitrile gloves
    • Face shield
    • Coverall or lab coat
  2. Do not open filled containers without EHS authorization.
  3. Emergency eyewash and shower stations must be nearby.

5.7 Spill and Incident Management

  1. Follow SOP/API/202/2025 for managing hazardous waste spills.
  2. Report incidents using the Hazardous Waste Incident Report Form (Annexure-5).

5.8 Training and Audit

  1. Quarterly training to be conducted for relevant staff.
  2. EHS shall audit segregation and storage areas monthly using the Hazardous Waste Audit Checklist (Annexure-6).

6. Abbreviations

  • SOP: Standard Operating Procedure
  • SDS: Safety Data Sheet
  • EHS: Environment, Health & Safety
  • DG: Dangerous Goods
  • CAPA: Corrective and Preventive Action

7. Documents

  1. Hazardous Waste Label – Annexure-1
  2. Hazardous Waste Register – Annexure-2
  3. Hazardous Storage Signage – Annexure-3
  4. Authorized Vendor List – Annexure-4
  5. Hazardous Waste Incident Report Form – Annexure-5
  6. Hazardous Waste Audit Checklist – Annexure-6

8. References

  • Hazardous and Other Wastes (Management and Transboundary Movement) Rules, 2016 – CPCB
  • GMP Guidelines – WHO, ICH Q9
  • EPA Guidelines for Chemical Waste Handling

9. SOP Version

Version: 2.0

10. Approval Section

Prepared By Checked By Approved By
Signature
Date
Name
Designation
Department

11. Annexures

Annexure-1: Hazardous Waste Label Format

Field Example Entry
Waste Description Spent Acetone
Hazard Class Flammable
Department API Production
Date of Generation 13/04/2025

Annexure-2: Hazardous Waste Register

Date Waste Type Quantity Location Disposed By
13/04/2025 Acetone 25 L Solvent Room Sunita Reddy

Annexure-3: Hazardous Storage Area Signage

Label: “DANGER – HAZARDOUS WASTE STORAGE AREA – AUTHORIZED PERSONNEL ONLY”
Font: Bold, red text on white background (A2 size)

Annexure-4: Authorized Vendor List

Vendor Name Approval No. Contact Region
EcoSafe Disposals Pvt. Ltd. CPCB/2025/014 +91-9876543210 Maharashtra

Annexure-5: Hazardous Waste Incident Report Form

Date Location Waste Type Cause Corrective Action
12/04/2025 Warehouse Acid Drum Leak Damaged Cap Replaced container & updated SOP

Annexure-6: Hazardous Waste Audit Checklist

Checkpoint Compliant (Yes/No) Remarks
Labeling Complete Yes All containers labeled
Storage Area Locked No Lock missing

Revision History:

Revision Date Revision No. Details Reason Approved By
01/01/2022 1.0 Initial Issue New SOP QA Head
14/04/2025 2.0 Annexures, vendor list, and audit checklist added GMP and CPCB Compliance QA Head
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